Farhad Shirini
Faculty: Faculty of Science
Department: Department of Chemistry
University of Guilan
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Farhad Shirini
Academic Rank:

Professor

Faculty:

Faculty of Science

Department:

Department of Chemistry



Profile :: Education :: Publications :: Courses :: CV :: Contact


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1. Ph.D., Organic Chemistry, Shiraz University, Shiraz, Iran (1991-1995)

Thesis title:

Part A: Synthesis of some stable derivatives of cyclobutadiene

Part B: New synthetic methodologies:

a: Some application of WCl6 in organic chemistry

b: Deprotection and oxidative deprotection of trimethylsilyl ethers

Supervisor: Professor Habib Firouzabadi

2. M.Sc., Organic Chemistry, Shiraz University, Shiraz, Iran (1988-1990)

Thesis title: Reactions of epoxides with one electron transfer agents

Supervisor: Professor Naser Iranpoor

3. B.Sc., Chemistry, Shiraz University, Shiraz-Iran (1983-1987)



1. Cerric ammonium nitrate, as an efficient catalyst ffor mild and selective opening of epoxides in the presence of water, thiols and acetic acid.

N. Iranpoor, I. M. Baltork, F. Shirini; Tetrahedron, 1991, 47, 9861.

2. Tris[trinitrato Ce(IV)]paraperiodate, as an efficient heterogeneous catalyst for alcoholysis, acetolysis and hydrolysis of epoxides.

N. Iranpoor, F. Shirini; Synth. Commun., 1994, 24, 1959.

3. Coupling of thiols and selenols catalyzed by tris[trinitrato cerium(IV)]paraperiodate.

N. Iranpoor, P. Salehi, F. Shirini; J. Org. Prep. and Procedure Int., 1995, 27, 216.

4. Deprotection and direct oxidative deprotection of trimethylsilyl ethers to corresponding alcohols and carbonyl compounds with [(NO3)3 Ce]3.H2IO6 in an aprotic solvent.

H. Firouzabadi, F. Shirini; Synth. Commun., 1996, 26, 423.

5. [(NO3)3 Ce]2 CrO4 vs [(NO3)3 Ce] CrO4.2H2O in the oxidation of trimethylsilyl ethers.

H. Firouzabadi, F. Shirini; Synth. Commun., 1996, 26, 649.

6. New applications of tungsten hexachloride (WCl6) in organic synthesis. Halo-dehydroxilation and dihalo-de-oxo-bisubstitution reactions.

H. Firouzabadi, F. Shirini; Tetrahedron, 1996, 52, 14929.

7. Highly efficient, regio- and stereoselective ring opening of epoxides with Ce(OTf)4.

N. Iranpoor, M. Shekarriz, F. Shirini; Synth. Commun., 1998, 28, 347.

8. Oxidation of benzyl alcohols and acyloins with (NO3)3CeBrO3.

F. Shirini, H. Tajik, A. Aliakbar, A. Akbar; Synth. Commun., 2001, 31, 767.

9. Polymer supported reagents: Oxidative selection between benzyl alcohols.

F. Shirini, H. Tajik, F. Jalili; Synth. Commun., 2001, 31, 2885.

10. [(NO3)3 Ce]3.H2IO6: As a veratile and efficient reagent for cleavage of carbonnitrogen double bonds under heterogeneous and non-aqueous conditions.

F. Shirini, M. R. Azadbar; Synth. Commun., 2001, 31, 3775.

11. Efficient solvent free deoximation and dehydrazonation with HIO3 in the presence of wet SiO2.

F. Shirini, M. A. Zolfigol, M. R. Azadbar; Synth. Commun., 2002, 32, 315.

12. Efficient cleavage of carbon-nitrogen double bonds under solvent free conditions.

F. Shirini, M. A. Zolfigol, A. Pourhabib; Synth. Commun., 2002, 32, 2837.

13. Efficient oxidation of sulfides to sulfoxides and of thiols to disulfides with aqueous HIO3.

F. Shirini, M. A. Zolfigol, M. M. Lakouraj, M. R. Azadbar; Rus. J. Org. Chem., 2001, 37, 1405.

14. Oxidation of benzyl alcohols under mild and heterogeneous conditions.

F. Shirini, M. A. Zolfigol, M. R. Azadbar; Rus. J. Org. Chem., 2001, 37, 1673.

15. ZrCl4/wet SiO2 promoted oxidation of alcohols by (NH4)2Cr2O7 in solution and solvent free conditions.

F. Shirini, M. A. Zolfigol, A. Pourhabib; J. Chem. Res.(S), 2001, 476.

16. Oxidation of benzyl alcohols by tris[trinitrato Ce(IV)]paraperiodate in solvent free conditions.

F. Shirini, A. Pouhabib, M. R. Azadbar; Asian J. Chem., 2001, 13, 1637.

17. Oxidation of alcohols by (NH4)2Cr2O7 in solution and solvent free conditions.

F. Shirini, M. A. Zolfigol, B. Mallakpour, S. E. Mallakpour, A. R. Hajipour; Australin J. Chem., 2001, 54, 405.

18. Oxidation of urazoles to their corresponding triazlinediones under mild and heterogeneous conditions via in siyu generation of NO+ IOx-.

M. A. Zolfigol, G. Chehardoli, F. Shirini, S. E. Mallakpour, H. Nasr-Isfahani; Synth. Commun., 2001, 31, 1965.

19. Chemoselective N-nitrosation of secondary amines under mild and heterogeneous conditions.

M. A. Zolfigol, A. Ghorbani Choghamarani, F. Shirini., H. Keypour, S. Salehzadeh; Synth. Commun., 2001, 31, 359.

20. Chemoselective N-nitrosation of secondary amines under mild and heterogeneous conditions via in situ generation of NOCl.

M. A. Zolfigol, F. Shirini, A. Ghorbani Choghamarani, A. Taqian-Nasab, H. Keypour,S. Salehzadeh; J. Chem. Res (S), 2000, 420.

21. Chemoselective N-nitrosation of secondary amines under mild and heterogeneous conditions with ZrCl4/ NaNO2.

M. A. Zolfigol, F. Shirini, A. Ghorbani Choghamarani, Azam Shiri, H. Keypour, S. Salehzadeh; Asian J. Chem., 2001, 13, 849.

22. Silica chloride/ NaNO2 as a novel heterogeneous system for the nitrosation of secondary amines under mild conditions.

M.A.Zolfigol, F. Shirini, A. G. Choghamarani; Synth. Commun., 2002, 32, 1809.

23. Coupling of thiols catalyzed by trinitratocerium(IV) bromate.

H. Tajik, F. Shirini, O. R. Farahkhah, M. M. Lakouraj, I. M. Baltork; Russian J. Org. Chem.; 2002, 38, 1435.

24. Redox polymerization of acrylonitrile initiated by the system tristrinitrato cerium(IV) paraperiodate propane-1,2-diol.

H. Dezhampanah, F. Shirini; Asian J. Chem., 2002, 14, 1111.

25. A mild and efficient method for cleavage of C=N using Mg(HSO4)2 in the presence of wet SiO2.

F. Shirini, M. A. Zolfigol, B. Mallakpour, S. E. Mallakpour, A. R. Hajipour, I. M. Baltork; Tetrahedron Lett., 2002,43,1555.

26. Solvent free oxidation of thiols by (NH4)2Cr2O7 in the presence of Mg(HSO4)2 and wet SiO2.

F. Shirini, M. A. Zolfigol, B. Mallakpour, I. M. Baltork, S. E. Mallakpour, A. R. Hajipour; J. Chem. Res(S), 2003, 1, 28.

27. Chemoselective solvent free deoximation by (NH4)2Cr2O7 in the presence of ZrCl4/wet SiO2.

F. Shirini, M. A. Zolfigol, A. Pourhabib; Russian J. Org. Chem., accepted for publication.

28. Efficient cleavage of C=N under heterogeneous and non-aqueous conditions.

F. Shirini, M. Mamaghani, F. Parsa, I. Mohammadpoor-Baltork, Bull. Korean Chem. Soc.; 2002, 23, 1683.

29.Silica chloride/ wet SiO2 as a novel heterogeneous system for deprotection of oximes,

hydrazones and semicarbazones.

F. Shirini, M. A. Zolfigol, M. Khaleghi, I. Mohammadpoor-Baltork; Synth. Commun., 2003, 33, 1839.

30. Polymer supported reagents: oxidative selection between thiols.

F. Shirini, M. M. Lakouraj, I. Mohammadpoor-Baltork, D. Asadi; Synth. Commun., 2003, 33, 1833..

31. Silica sulfuric acid/ NaNO2 as a novel heterogeneous system for the oxidation of 1,4- dihydropyridines under mild conditions.

M. A. Zolfigol, F. Shirini, A. Ghorbani Choghamarani, I. Mohammadpoor-Baltork; Green Chem.,2002, 4, 562.

32. Mild and efficient method for reduction of aldehydes and ketones with NaBH4 in the presence of Dowex-1X8.

B. Zeynizadeh, F. Shirini; J. Chem. Res.(S), 2003, 335.

33. Prolinium chlorochromate as a new mild and efficient oxidant for alcohols.

M. Mamaghani, F. Shirini, F. Parsa; Russian J. Org. Chem., 2002, 38, 1113.

34. Oxidative coupling of thiols by silica supported prolinium chlorochromate.

M.Mamaghani, F. Shirini, F. Parsa, I. Mohammadpoor-Baltork; Russian J. Org. Chem., accepted for publication.

35. Silica chloride/NaNO2 as a novel heterogeneous system for the production of thinitrites and disulfides under mild conditions.

M. A. Zolfigol, F. Shirini, A. Ghorbani Choghamarani, E. Ghofrani; Phosphorous, Sulfur and Silicon and the related elements, 2003, 178, 1477.

36. Acetyl-tethering silica as a novel reagent for acetylation of alcohols under mild and heterogeneous conditions.

F. Shirini, M. A. Zolfigol, K. Mohammadi; Bull. of Korean Chem. Soc., 2003, 24, 519.

37. Caffeinilium chlorochromate: as a mild and efficient reagent for oxidation of alcohols and chemoselective oxidative cleavage of oximes.

F. Shirini, I. Mohammadpoor-Baltork, Z. Hejazi, P. Heravi; Bull. of Korean Chem. Soc., 2003, 24, 517.

38. Acetylation and formylation of alcohols in the presence of silica sulfuric acid.

F. Shirini, M. A. Zolfigol, K. Mohammadi; Phosphorus, Sulfur, and Silicon and the related elements, 2003, 178, 1617.

39. A mild and efficient method for chemoselective silylation of alcohols using hexamethyldisilazane in the presence of silica chloride.

F. Shirini, M. A. Zolfigol, K. Mohammadi; Phosphorus, Sulfur, and Silicon and the related elements, 2003, 178, 1567.

40. Efficient oxidation of alcohols with KBrO3 in the presence of silica chloride and wet SiO2.

F. Shirini, M. A. Zolfigol, M. Khaleghi; Phosphorus, Sulfur, and Silicon and the related elements, 2003, 178, 2107.

41. Silica chloride / NaNO2 as a novel heterogeneous system for the oxidation of 1,4-dihydropyridines under mild conditions via in-situ generation of NOCl.

M. A. Zolfigol, F. Shirini, A. Ghorbani Choghamarani, I. Mohammadpoor-Baltork; Phosphorus, Sulfur, and Silicon and the related elements, 2003, 178, 1709.

42. Silica chloride as a mild and efficient reagent for acetylation of alcohols.

F. Shirini, M. A. Zolfigol, M. Khaleghi; Phosphorus, Sulfur, and Silicon and the related elements, 2003, 178, 1999.

43. Silica chloride/ NaNO2 as a novel heterogeneous system for the nitration of phenols under mild conditions.M. A. Zolfigol, F. Shirini, A. G. Chogamarani; Phosphorus, Sulfur, and Silicon and the related elements, 2003, 178, 2019.

44. Mild and efficient reduction of α,β-unsaturated carbonyl compounds, α-diketones and acyloins with sodium borohydride/Dowex 1-X8 system.

B. Zeynizadeh, F. Shirini; Bull. Korean Chem. Soc., 2003, 24, 295.

45. Silica sulfuric acid as an efficient reagent for the synthesis of symmetrical ethers under mild and heterogeneous conditions.

F. Shirini, M. A. Zolfigol, K. Mohammadi; Phosphorus, Sulfur, and Silicon and the related elements, 2003, 178, 2357.

46. Oxidation of alcohols using (NH4)2Cr2O7 in the presence of silica chloride/wet

SiO2 in solution and under solvent free conditions.

F. Shirini, M. A. Zolfigol, M. Khaleghi; Bull. Korean Chem. Soc., 2003, 24, 1021.47. Mg(HSO4)2 as a mild and efficient reagent for acetylation of alcohols.

F. Shirini, M. A. Zolfigol, B. Mallakpour; Int. J. Chem. Sci., 2003, 1, 53.

48. Silica sulfuric acid as a mild and efficient reagent for the acetylation of alcohols in solution and under solvent free conditions.

F. Shirini, M. A. Zolfigol, K. Mohammadi; Bull. Korean Chem. Soc., 2004, 25, 325.

49. Al(HSO4)3 as a efficient catalyst for the acetylation of alcohols in solution and under solvent free conditions.

F. Shirini, M. A. Zolfigol, M. Abedini; Monatshefte fur Chemie, 2004, 135, 279.

50. Silica sulfuric acid/wet SiO2 as a novel heterogeneous system for cleavage of C=N bonds under mild conditions.

M. A. Zolfigol, B. F. Mirjalili, F. Shirini, et al; Phosphorus, Sulfur, and Silicon and the related elements, 2003, 178, 2735.

51. Regeneration of carbonyl compoundsby cleavage of C=N bonds under mild and completely heterogeneous conditions.

F. Shirini, M. A. Zolfigol, A. Safari, I. Mohammadpoor-Baltork, B. F. Mirjalili; Tetrahedron Lett., 2003, 44, 7463.

52. A mild and efficient method for acetylation and formylation of alcohols using Mg(HSO4)2.

F. Shirini, M. A. Zolfigol, B. Mallakpour; Russ. J. Org. Chem., accepted for publication.

53. Al(HSO4)3 catalyzed acetylation and formylation of alcohols.

F. Shirini, M. A. Zolfigol, M. Abedini, P. Salehi; Bull. Korean Chem. Soc., 2003, 24, 1683.

54. Oxidation of alcohols using (NH4)2Cr2O7 in the presence of Al(HSO4)3 and wet SiO2.

F. Shirini, M. A. Zolfigol, M. Abedini, P. Salehi; Mendeleev Commun., 2003, 265.

55. Oxidative coupling of thiols in solution and under solvent free conditions.

F. Shirini, M. A. Zolfigol, M. Khaleghi; Mendeleev Commun., 2004, 34.

56. Polymer supported reagents: A mild and efficient method for oxidation of alcohols.

F. Shirini, M. Dabiri, S. Dezyani, F. Jalili; Russ. J. Org. Chem., accepted for publication.

57. Zirconium borohydride piperazine complex, an efficient, air and thermally stable reducing agent.

M. Tajbakhsh, M. M. Lakouraj, F. Shirini, S. Habibzadeh, A. Nikdoost; Tetrahedron Lett., 2004, 45, 3295.

58. Silica phosphoric acid/NaNO2 as a novel heterogeneous system for the coupling of thiols to their corresponding disulfides.

M. A .Zolfigol, F. Shirini, K. Zamani, E. Ghofrani, S. Ebrahimi; Phosphorus, Sulfur, and Silicon and the related elements, accepted for publication.

59. Oxidative selection between alcohols under solvent free conditions.

F. Shirini, A. Safari; International J. Chem. Sci., accepted for publication.

60. A mild and efficient method for the acetylation of alcohols.

F. Shirini, M. A. Zolfigol, A .Safari; Indian J. Chemistry, Section B, accepted for publication.

61. Al(HSO4)3 as an efficient reagent for the selective trimethylsilylation of primary alcohols under solvent free conditions.

F. Shirini, M. A. Zolfigol, M Abedini; Phosphorus, Sulfur, and Silicon and the related elements, accepted for publication.



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shirini@guilan.ac.ir
Department of Chemistry,
College of Science,
University of Guilan
Rasht-Iran
Phone: +98 131 3226643
Fax:+98 131 3220066
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